Journals

S/N Title Author(s) Abstract Journal Document
101 Hydrogeochemical Characterisation and Groundwater Quality appraisal of the shallow underground waters of Southern Iullemmeden (Sokoto) Basin, Northwestern, Nigeria Okunlola, O. A. and Olatunji, A. S.

The sediments of Sokoto basin were deposited during the continental Mesozoic and Tertiary phases, with an intervening marine Maastrichtian to Palaeocene phase. The considerable lithological variations and occurrence of industrial minerals in the basin necessitates the quest to characterise and determine the quality of the groundwater in some of the formations to ascertain the impact of these variations on the groundwater character and chemistry. Fifty-three paired groundwater samples were collected from boreholes and hand dug wells sunk into the Gundumi, Kalambaina, Rima and the Gwandu formations of the basin. for anion and cation analysis. The TDS, pH, temperatures, and electrical conductivity (EC) were determined on the field using a portable digital meter. The anions were determined by titrimetric methods while the cations were determined using the UV spectroscopy method. The results show that for the Gundumi samples, cationic concentration is in the order Na>Ca>K>Mg ,while the anion concentration is in the order HCO3> SO3>Cl> NO3; that of Rima formation showed the order of cationic abundance to be Mg>Ca>Na>K while that of the anion is in the order HCO3> SO4 >Cl> NO3; the Kalambaina formation samples an order of cationic abundance to be Ca>Na>K>Mg while that of the anions is in the order NO3>HCO3>Cl>SO4 and the samples from Gwandu formation. The order of cationic abundance for the Gwandu formation water samples is Mg>Ca>Na>K while that of the anions is in the order HCO3> SO4> Cl >NO3. Further geochemical characterization of the water samples showed that water samples from Kalambaina formation are predominantly Ca-HCO3 water type; that of Gwandu are a combination of Na-HCO3 and Ca-HCO3 water types, the Gundumi samples are predominantly Na-HCO3 and Na- Cl water types and the samples from Rima formation are predominantly Ca-HCO3 water type. The plots of the Log of TDS versus the ratio of Na/ (Ca+Na) for the water samples also show that the groundwater samples from all the formations had been influenced more by the by the action of weathering than dilution and evaporation, a strong indication that the groundwater samples had interacted effectively with the lithologic units that constituted the aquifer materials. The calculated Ca/Mg ratio of water samples obtained from the Kalambaina formation gave values greater than four (>4) signifying a Limestone dominated aquifer. The various results indicate that the groundwater character and quality from within the basin are determined by rock-water interactions, agricultural as well as other human activities. The rock-water interactions had resulted in the dissolution and leaching of the aquifer materials by the groundwater system while the presence of abundant nitrate in some of the groundwater samples is an indication of the leaching of fertilizers into the ground water system especially in the very porous and permeable formations.

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102 Reliability of Geophysical Techniques in the Evaluation of Aquifer Vulnerability at Igbo- Imabana, Cross River Sate, Nigeria using Electrical Resistivity Method Obasi, P. N., Ekinya, E. A., and Eyankware, M.O.

An investigation has been made of the groundwater potentials of Igbo-Imabana, Abi L.G.A of Cross River State, Nigeria, using electrical resistivity survey. This study was motivated to determine the electrical resistivity parameters of the area. This work aims to use the electrical resistivity method to explore the groundwater potentials of the study area with the determination of its second-order parameters. A total of fifteen vertical electrical soundings (VES) were conducted with a maximum electrode spacing of 400 m. The data was acquired using ABEM SAS 4000 Terrameter and processed using Interpex software. The interpreted and analyzed results reveal four to six geoelectric layers. The VES curves obtained were Q, H, A, QH, KH, KQ, and KHK. From the result, the Dar Zarrouk parameters longitudinal conductance (S) and transverse resistance (Tr) were calculated. The longitudinal conductance and transverse resistance range between 0.0022 to 2.81 ohms, and 36.59 to 86102.9 Ω/m2 respectively. Further findings revealed that the hydraulic conductivity (Kc) values range from 7.95×10-4 to 2.06×10-3 m/day while, transmissivity values vary between 8.25 x 10-3and 2.82 m2/day. Findings from the calculated parameters suggested that the study area has moderate to good groundwater prospects at certain VES points. However anthropogenic activities that pose a threat to aquifer contamination should be closely monitored by relevant bodies.

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103 Potentials of Morphometric Parameters in The Assessment of Groundwater and Conservation Strategies in The Niger Delta: Niger South, Ha5 Yarima, L.C.

The study on the potentials of morphometric parameters in the assessment of groundwater and conservation strategies in the Niger Delta was successfully done. The ArcGIS 10.1 software was used for calculation, delineation, and morphometric analysis of the catchment from Shuttle Radar Topography Mission (SRTM) Digital Elevation Model (DEM). The morphometric attributes and runoff relationship was explored for the determination of linear, aerial, and relief aspects of the drainage networks. The DEM derived information revealed a drainage density of 0.3 which indicates low stream frequencies and sparse drainage network. Low drainage density is a favourable terrain for infiltration and groundwater recharge. The infiltration number of 2.97 is moderate and shows potential for active infiltration. A drainage texture 3.3 indicates a coarse texture. This attribute has positive correlation with the drainage density in promoting groundwater recharge. The elongation ratio of 0.65 suggests that the basin belongs to the elongated types and implies a longer duration of the overland flow which offers an advantage to groundwater recharge. The length of overland flow 1.7 indicates a less structural disturbance, and less runoff conditions are good factors for water percolation into the soil. The Constant of channel maintenance (C) 3.3 means an average of 3.3km2 surface area is needed for the creation of one linear km of stream. This implies the soil is porous with a potential land subsidence, erosion, river bank failure and possibility of intrusion of foreign material into the underground water. The relief ratio (Rh) value of 1.29 shows HA5 has a gentle slope. This is a factor to slow runoff, thus, favouring groundwater recharge. The natural and anthropological impacts ranging from saltwater intrusion and effluentrelated contamination from oil spillage, gas flaring, municipal, industries and agriculture will aggravate the contemporary water conditions in the basin and more pressure on the available freshwater. Therefore, concerted efforts are required for proper conservation of the ecosystem and pollution load reduction to engender improved freshwater availability in the basin.

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104 Modelling Groundwater Quality Potential in GIS Environment Within Bayero University Kano New Campus and Environs Sarki, A. A., Umar, N. U., Arabi, A. S., Abdullahi, I. M., Girie, M. B., and Sule, G.

This paper describes an important contribution towards understanding ground water quality using GIS application. One of the objectives of the study is to assess water quality status in Bayero University Kano and environs. Secondly, an attempt to determine the spatial distribution of ground water quality parameters which shows or identifies areas with the best quality drinking water within the study area. The method adopted combination of water quality index (WQI) and Geographical Information System (GIS) application to achieve the set objectives. Maps showing spatial distribution of water quality parameters such as SO₄, TDS, pH, Na, HCO₃, Ca, Mg, Fe, CO₃, NO₃ and Total hardness were analysed using a simple kriging method in ArcGIS 10.8.2 environment. Water quality assessment falls within “Good”, “Poor” and “Very Poor” quality for drinking categories. The results indicates that, there is a variation in terms of water quality for drinking using WHO and NESREA water quality standards in the areas sampled. This paper provides the fact that, WQI and GIS application provides a comprehensive result which shows areas with higher and lower drinking water quality. This approach will help decision makers plan a better approach in operation and maintenance of groundwater resources.

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105 Hydrogeochemical Approach of Groundwater Evaluation of the Effects of Mining in the Enyigba Mining District, Southeast Nigeria Philip Obasi; Akpa, Chibuike; Emmanuel Udomiaye; Omeokachie Adolphus; Eunice Eme, Nweke Obisi Samuel, Ovu and Ifeanyi Alieze

Hydrochemical approach has been used to study and to appraise the features that control the groundwater characteristics and chemical attributes in the Enyigba mining district. Atomic Absorption Spectrophotometric method was used to analyse twenty groundwater samples collected from the area. Results were further subjected to geochemical parameters including Ion Exchange, Soltan’s, Diamond, Parson, Flickin, Gibbs, and Chadba’s plots. The result showed acidic to basic waters (pH ranges from 3.34 to 7.0). The concentration of heavy metals is Cd>Hg> Pb>Co>Mn. Soft to moderate water has been deduced with Ca+Mg and SO4+Cl, Ca-Mg-Cl, Na+ + HCO3¯ water types in the area. Geochemical studies indicate rock-water interaction and ion exchange due to the dissolution of silicate sand carbonate weathering as the major factor that influences groundwater evolution in the area. Deduction from Soltan’s classification revealed a deep meteoric water type for the groundwater within the area. Potential health effects have been opined due to the carcinogenicity and toxicity of heavy metals.

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106 Bathymetry Study of the Siltation Level in Ayede Dam Reservoir in Ekiti State, Nigeria. Omozeje, E. F.

Siltation can either be gradual or fast depending on the rate and provenance of sediments which can adversely affect a dam reservoir capacity. Measuring and determination of siltation level in a dam reservoir is not always an easy task but requires systematic approach because of the environment. Bathymetry survey is one the method that can be used to measure the amount of siltation in a dam reservoir and was carried out at Ayede Dam to determine the level of siltation at the dam reservoir. It is a small dam with a height of 13 meters, crest length of 326m, and a holding reservoir capacity of 1.5 million cubic meters of water at completion in 1979. Results obtained from the investigation indicated a heavily silted dam reservoir as the reservoir capacity has shrunk from original designed capacity of 1,500,000 m3 to 191, 270.59m3. About 87% of the designed capacity have been lost to siltation which may have been gradual. Sedimentary infilling of the dam reservoir has reached advance stage. The highest water depth recorded from the bathymetry survey is 3.52m as against 11.5m at completion. The result clearly shows a heavily silted reservoir and hence the urgent need to de-silt the reservoir and improve its capacity for socio-economic development.

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107 Application of Electrical Resistivity Profiling method of a proposed Earth Dam; A case study of Otuo Earth Dam Edo State, Nigeria Omozeje, E. F. and Aizebeoje, A. J.

Electrical resistivity profiling method using the Wenner configuration was employed in conducting horizontal resistivity profiling along the proposed Otuo dam axis with a view of determining rock stratification, orientation, fractures, and lineaments across the proposed dam axis. Result provided by the geophysical investigation should guide in geotechnical investigation along the dam axis and subsequently depth of excavation and treatment of subsurface fissures and cracks. Geoelectric layers encountered can be classified into three groups (low resistivity layers 147 - 334 Ωm, high resistivity layer 504 – 701 Ωm and remarkably high resistivity layer 1149 – 2617 Ωm). From 35 and 96 meters on ERP 1, the basement is concealed by a very conductive material with over 12 meters thick in places. Resistivity values indicate that the material is silt and clayey silt as a major constituent. These materials may be unsuitable as foundation materials / dam construction. In ERP 2, a very conductive zone was observed between 20 – 28m and the layer appears to be concealed by highly resistive layer 5 meters below extending from 20 – 120m and the start to dip. The orientation of the basement rocks from the resistivity section indicates a possible joint or fracture exist between 20 – 28m.

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108 Aspect of Geochemical and Water Quality Studies of Parts of Southern Bida Basin, Southwestern, Nigeria Olaleye I. M., Ige O. O., and Okeke C. J.

This study aims at assessing geochemical characteristics and water quality status of water samples from parts of Southern Bida basin in order to identify the physicochemical characteristics, hydrochemical facies, and geochemical signatures of the water sources through analyses and indepth discussion of eighty-three (83) groundwater samples. pH, electrical conductivity, total dissolved solids, sodium, potassium, chloride, and bicarbonate, had average values of 6.2, 344.8 μS/cm, 179.6mg/l, 31.2mg/l, 30mg/l, 44mg/l, and 84.8mg/l, respectively. Rock-water interaction is the main determinant of groundwater chemistry, and CaHCO3 is the dominant groundwater facies. Indicating the dominance of alkalis over alkaline earth elements, the chloro-alkaline indices show that 90% of the samples are undergoing reverse cation exchange reactions. Geochemical modeling using saturation index revealed that groundwater is under-saturated in comparison to the surrounding system. Total dissolved solids (TDS) measured in the samples have positive correlation coefficients of 0.66, 0.63, 0.73, and 0.85 with Na, K, SO4, and Cl respectively. This suggests that these major ions are the major sources of TDS. Three factors were identified through factor analysis: A, B, and C which account for 41%, 20% and 9% of the total variance respectively. A comparison of the ion concentrations with globally accepted recommended values revealed that 90% of the parameters were generally within acceptable ranges and thus suitable for drinking except restricted elevation of chloride while 85% of the groundwater sample fell within the suitability range of the irrigation suitability charts.

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109 Effectiveness of the Existing Strategies for Managing Marine Transportation Incidences and Socio-Economic Implications Ogboeli G. P., Iyama, W. A., Onuegbu W., Dollah C. O., Gbode L. and Timothy N.

The study investigated the effectiveness of the existing strategies for managing marine transportation incidence alongside socio-economic impacts in Nigeria. Four hundred copies of questionnaire were administered on the respondents drawn from all maritime regulatory agencies, including Nigerian Shipping Council, Nigerian Maritime Administration and Safety Agency, Nigerian Inland and Waterways, Nigerian Ports Authority and Maritime Police with the use of simple random technique. The Study affirmed availability of strategies for managing maritime transportation incidence in Nigeria however not in full usage hence these strategies are very ineffective. Socio-economic implications were obvious and there is need to curb the negative impacts through government deliberate actions and policies. It is pertinent to state that the study results admit the challenges arising from marine incidences, the non-implementation of existing strategies for management of marine related incidences by ministries, departments and agencies saddled with the responsibilities of maritime protection and management tends to be a major cause of most marine incidences. Hence, for a better maritime protection and management, there is need for these strategies adopted by different MDA’s to implemented and effectively monitor the trend. Hence study recommends enforcement of maritime management strategies amongst maritime based Ministries, Department and Agencies should be given top priority.

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110 Assessment of Groundwater Quality Using Water Quality Indices in Lere and Environs, Kaduna State, North Western Nigeria Michaels, P. S., and Eduvie, M. O.

The assessment of groundwater quality using water quality indices was done to determine if the groundwater was suitable for irrigation and for domestic purposes. 30 groundwater samples were taken from various locations and analysed for different parameters which include TDS, DO, pH, EC, SO4, Cl, HNO3, NO3, Mg, Ca and PO4. For drinking water purposes, the WQI was determined with the aid of various equations the results of which was used to produce the WQI map. The SAR, Na % and PI were used to evaluate the quantity of soluble salts in groundwater that are ionized. With the WQI and WHO guidelines values, about 40% of the sample exhibit good groundwater quality for residential use and for its suitability for irrigation assessment reveals that the groundwater in the study area is appropriate for irrigation.

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